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Matt Framer, a graduate student at Baylor
University, working
at ORNL under the direction of Lynn Boatner of the Solid State
Division,
is studying alkali lanthanide double phosphates for radiation detection
applications.
Current research has focused on K3Lu(PO4)2 and previous
characterization
with single crystal x-ray diffraction and neutron powder diffraction
has
provided evidence of low temperature phase transitions. With the High
Flux
Isotope Reactor currently down for upgrades low temperature
capabilities
for studying structural information of powders is limited, however, the
HTML
beamline at the National Synchrotron Light Source offers such
capabilities.
Data were collected at 293, 230, 200, 100 and 30 K and the low
temperature
polymorphs have been confirmed. Rietveld refinements are being used to
understand
these low temperature structures. A poster titled “Polymorphism, Phase
Transitions,
and Thermal Expansion of K3Lu(PO4)2” by J. Matt Farmer, Lynn Boatner,
Bryan
Chakoumakos, Claudia Rawn, and Jeff C. Bryan received both the Pauling
Poster
Prize and the 2001 Oxford Poster Prize at the Annual Meeting of the
American
Crystallographic Association in Los Angeles in July 2001. This is
especially
significant in that it is the first time that both awards have been
given
for the same poster.
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